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Environmental Exposure Effects on Polymers

Ageing is defined as 'long-term chemical and physical changes during service which lead to component property degradation or failure'.

MERL has considerable experience and facilities for the assessment of environmental effects on polymers, rubbers, composites and adhesive bonding systems. MERL has a series of thermal ageing ovens and pressure vessels for conducting elevated temperature environmental exposures. Thermal cabinets can also be placed on test machines.

Tests can be performed on:

  • Test samples to ISO/ASTM/BSI etc
  • Standard components
  • Structures and sub-structures

Environments that can be studied at ambient, cold or elevated temperatures include:

  • Oils & hydrocarbons
  • Alcohols & solvents
  • Salt water
  • Production fluids
  • De-scalers, de-waxers
  • De-icers

Why consider environmental effects?

  • At higher temperatures many materials become weaker and age more quickly
  • Elastomers with higher temperature resistance tend to be weaker
  • New materials proposed for higher temperature resistance need to be assessed
  • Increasing reliability requirements
  • Increasing under-hood/bonnet temperature in automotive applications
  • Higher temperature in down hole oil production
  • Increased use of composites in super sonic aerospace applications

 


Key aspects of service environment

  • Temperature cycles (thermal history)
  • Temperature extremes
  • Static load (continuous)
  • Dynamic load (Intermittent)
  • Oxygen, ozone, oil, fuel
  • Need to consider

  • Physical effects - creep, fatigue
  • Chemical effects - anaerobic ageing, oxidation, ozone
  • Interactions - e.g. chemical ageing on creep, stress on rate of chemical ageing (see figure right)
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    Example of temperature/ageing interaction

    Example Arrhenius plot

     

    A distinction must be made between anaerobic ageing and oxidation.

    Oxidation may be 'diffusion controlled' i.e. by the rate that at which oxygen can diffuse into the material - e.g. in creep.

     
     

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    Tel: +44(0)1462 427 850
    Polymer Engineering, Testing, Inspection, Research and Development, UK